And my suggestion of the best ones.
You can’t choose which player skills will players develop when playing Master league. But it can be a factor that will help you decide which player will play in which game.
Here’s how to access Player skills menu (ignore the red arrow):
And here’s a complete list of player skills. I’ve marked those which I think are the most useful (for the best results) with red.
To find out how to use knuckle shot in a combo with advanced shooting, read this article.